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Venus Williams was sent crashing out of the Bausch & Lomb Championships after suffering defeat against France's Tatiana Golovin.
Five-time Grand Slam champion Williams is looking to re-establish herself as a dominant player on the WTA Tour after recovering from a left wrist injury, but she was comfortably beaten by 19-year-old Golovin on Friday.
The eighth seed dominated throughout to condemn home favourite Williams to a 6-2 6-3 defeat and set up a semi-final clash against Ana Ivanovic.
Ivanovic had earlier beaten Jelena Jankovic 7-5 6-3 to ensure her progress while Sybille Bammer defeated Daniel Hantuchova 2-6 6-2 6-2.
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